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247 questions
CAIEAS Level9701-as · Paper 1

Group 17

247 questions· page 1 of 25

Q192025 Feb/Mar·P121MMedium-Easy

U, V and W represent different halogens. The table shows the results of nine experiments in which aqueous solutions of U2\text{U}_2, V2\text{V}_2 and W2\text{W}_2 were separately added to separate aqueous solutions containing U\text{U}^-, V\text{V}^- and W\text{W}^- ions.

U(aq)\text{U}^-(\text{aq})V(aq)\text{V}^-(\text{aq})W(aq)\text{W}^-(\text{aq})
U2(aq)\text{U}_2(\text{aq})no reactionno reactionno reaction
V2(aq)\text{V}_2(\text{aq})U2\text{U}_2 formedno reactionW2\text{W}_2 formed
W2(aq)\text{W}_2(\text{aq})U2\text{U}_2 formedno reactionno reaction

Which row contains the ions U\text{U}^-, V\text{V}^- and W\text{W}^- in order of their decreasing strength as reducing agents?

Options

strongest \longrightarrow weakest
AU\text{U}^-V\text{V}^-W\text{W}^-
BU\text{U}^-W\text{W}^-V\text{V}^-
CV\text{V}^-W\text{W}^-U\text{U}^-
DW\text{W}^-U\text{U}^-V\text{V}^-
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Q232025 Feb/Mar·P121MMedium-Easy

Which graph correctly describes a trend found in Group 17?

[X represents a halogen atom.]

Options

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Q182025 May/Jun·P111MMedium

Three statements about the halogens, chlorine, bromine and iodine and their compounds are listed.

  1. The halogen with the highest boiling point has atoms which form the strongest bond to hydrogen.
  2. The halogen with the strongest instantaneous dipole (id–id) attractions forms the most thermally stable hydrogen halide.
  3. The most volatile element most rapidly oxidises hydrogen.

Which statements are correct?

Options

A   1 and 2
B   1 only
C   2 and 3
D   3 only

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Q192025 May/Jun·P111MMedium-Easy

Which reagent or reagents and conditions will oxidise chlorine, Cl2\text{Cl}_2, into a compound containing chlorine in the +5 oxidation state?

Options

A   AgNO3(aq)\text{AgNO}_3(\text{aq}) followed by NH3(aq)\text{NH}_3(\text{aq}) at room temperature
B   concentrated H2SO4\text{H}_2\text{SO}_4 at room temperature
C   cold dilute NaOH(aq)\text{NaOH}(\text{aq})
D   hot concentrated NaOH(aq)\text{NaOH}(\text{aq})

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Q172025 May/Jun·P121MEasy

Why do the halogens become less volatile as Group 17 is descended?

Options

A   The halogen–halogen bond energy decreases.
B   The halogen–halogen bond energy increases.
C   The number of electrons in each molecule increases.
D   The van der Waals’ forces between molecules become weaker.

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Q202025 May/Jun·P121MMedium-Easy

Sodium bromide is warmed with concentrated sulfuric acid.

Which row describes the change in the oxidation number of the sulfur and the role of the bromide ions in the reaction?

Options

change in oxidation number of sulfurrole of bromide ions
A+6 to +4oxidising agent
B+6 to +4reducing agent
C+4 to 0oxidising agent
D+4 to 0reducing agent
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Q172025 May/Jun·P131MEasy

Mixing aqueous silver nitrate and aqueous sodium chloride produces a precipitate.

Addition of which reagent to the mixture gives a colourless solution?

Options

A   aqueous ammonia
B   aqueous potassium iodide
C   dilute hydrochloric acid
D   dilute nitric acid

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Q192025 May/Jun·P131MMedium-Easy

Which statement about the properties of halogens and hydrogen halides is correct?

Options

A   A chloride ion is a stronger reducing agent than an iodide ion.
B   Chlorine is more volatile than bromine because chlorine has stronger intermolecular forces.
C   Hydrogen bromide is more thermally stable than hydrogen iodide because it has a stronger covalent bond.
D   Iodine is less reactive than bromine because iodine has weaker covalent bonds.

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Q182025 May/Jun·P141MMedium-Easy

Which row is correct?

Options

propertyexplanation
AAgI dissolves in aqueous ammonia more readily than AgCl doesAgI reacts with aqueous ammonia
BHCl decomposes more readily than HI doesCl is more electronegative than I
CI₂ has a higher melting point than Cl₂I₂ has stronger van der Waals' forces than Cl₂
DI₂ is a stronger oxidising agent than Cl₂an I atom loses electrons more readily than a Cl atom
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Q232025 May/Jun·P141MMedium-Easy

Which anions are formed when chlorine is passed into cold aqueous potassium hydroxide?

Options

A   Cl⁻ and ClO⁻
B   Cl⁻ and ClO₃⁻
C   Cl⁻ and ClO₄⁻
D   ClO⁻ and ClO₃⁻

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