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195 questions
Chemistry/Paper 2/Atoms, Molecules and Stoichiometry
CAIEAS Level9701-as · Paper 2

Atoms, Molecules and Stoichiometry

195 questions· page 1 of 20

Q12017 May/Jun·P223 partsEasy
(a)

Complete the table.

atomic numbernucleon numbernumber of electronsnumber of protonsnumber of neutronssymbol
3236Li+^{6}_{3}\text{Li}^{+}
232632
(b)(i)

Define the term relative isotopic mass.

(b)(ii)

Calculate the relative isotopic mass of 11B^{11}\text{B}.

Give your answer to six significant figures. Show your working.

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Q12016 Oct/Nov·P218 partsEasy
(a)

Calculate the amount, in moles, of hydrochloric acid used in the titration to neutralise the unreacted sodium hydroxide solution.

amount=............................ mol\text{amount} = \text{............................ mol}
(b)

Write the equation for the reaction between hydrochloric acid and sodium hydroxide.

(c)

Calculate the amount, in moles, of sodium hydroxide neutralised in the titration.

amount=............................ mol\text{amount} = \text{............................ mol}
(d)

Calculate the amount, in moles, of sodium hydroxide that reacted with the HCl\text{HCl} produced by the reaction in equation 1.

amount=............................ mol\text{amount} = \text{............................ mol}
(e)

Calculate the amount, in moles, of HCl\text{HCl} produced by the reaction in equation 1.

amount=............................ mol\text{amount} = \text{............................ mol}
(f)

Calculate the amount, in moles, of XCl4\text{XCl}_4 in the original 0.17 g0.17\text{ g} sample.

amount=............................ mol\text{amount} = \text{............................ mol}
(g)

Calculate the molecular mass, MrM_{\text{r}}, of XCl4\text{XCl}_4.

Mr=............................M_{\text{r}} = \text{............................}
(h)

Calculate the relative atomic mass, ArA_{\text{r}}, of X\text{X} and suggest its identity.

Ar of X=............................identity of X.............................................\begin{aligned} A_{\text{r}} \text{ of X} &= \text{............................} \\ \text{identity of X} &\quad \text{.............................................} \end{aligned}
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Q12016 Oct/Nov·P228 partsEasy
(a)

Calculate the amount, in moles, of hydrochloric acid present in 40.0 cm340.0\text{ cm}^3 of 1.00 mol dm31.00\text{ mol dm}^{-3} HCl\text{HCl}.

(b)(i)

Write the equation for the complete reaction of sodium carbonate with hydrochloric acid.

(b)(ii)

Calculate the amount, in moles, of sodium carbonate needed to react with the hydrochloric acid in the 10.0 cm310.0\text{ cm}^3 sample from the volumetric flask.

(b)(iii)

Calculate the amount, in moles, of hydrochloric acid in the 10.0 cm310.0\text{ cm}^3 sample.

(b)(iv)

Calculate the total amount, in moles, of hydrochloric acid remaining after the reaction shown in equation 1.

(b)(v)

Use your answers to (a) and (b)(iv) to calculate the amount, in moles, of hydrochloric acid that reacted with the 0.50 g0.50\text{ g} sample of M.

(b)(vi)

Use your answer to (v) and equation 1 to calculate the amount, in moles, of M in the 0.50 g0.50\text{ g} sample.

(b)(vii)

Calculate the relative atomic mass, ArA_r, of M and identify M.

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Q12016 Oct/Nov·P238 partsEasy
(a)

Calculate the amount, in moles, of hydrochloric acid used in the titration to neutralise the unreacted sodium hydroxide solution.

(b)

Write the equation for the reaction between hydrochloric acid and sodium hydroxide.

(c)

Calculate the amount, in moles, of sodium hydroxide neutralised in the titration.

(d)

Calculate the amount, in moles, of sodium hydroxide that reacted with the HCl\text{HCl} produced by the reaction in equation 1.

(e)

Calculate the amount, in moles, of HCl\text{HCl} produced by the reaction in equation 1.

(f)

Calculate the amount, in moles, of XCl4\text{XCl}_4 in the original 0.17 g0.17\text{ g} sample.

(g)

Calculate the molecular mass, MrM_r, of XCl4\text{XCl}_4.

(h)

Calculate the relative atomic mass, ArA_r, of X\text{X} and suggest its identity.

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Q22012 May/Jun·P218 partsEasy
(a)

Ammonium sulfate reacts with NaOH\text{NaOH} in a 1:21:2 ratio.

Complete and balance the equation for this reaction.

(NH4)2SO4+2NaOHNH3++(\text{NH}_4)_2\text{SO}_4 + 2\text{NaOH} \rightarrow \dots\dots\text{NH}_3 + \dots\dots\dots\dots\dots\dots\dots + \dots\dots\dots\dots\dots\dots\dots
(b)(i)

Write a balanced equation for the reaction between NaOH\text{NaOH} and HCl\text{HCl}.

(b)(ii)

Calculate the amount, in moles, of HCl\text{HCl} in 31.2 cm331.2\text{ cm}^3 of 1.00 mol dm31.00\text{ mol dm}^{-3} HCl\text{HCl}.

(b)(iii)

Calculate the amount, in moles, of NaOH\text{NaOH} in 50.0 cm350.0\text{ cm}^3 of 2.00 mol dm32.00\text{ mol dm}^{-3} NaOH\text{NaOH}.

(b)(iv)

Use your answers to (i), (ii) and (iii) to calculate the amount, in moles, of NaOH\text{NaOH} used up in the reaction with (NH4)2SO4(\text{NH}_4)_2\text{SO}_4.

(b)(v)

Use your answer to (iv) and the equation in (a) to calculate the amount, in moles, of (NH4)2SO4(\text{NH}_4)_2\text{SO}_4 that reacted with NaOH\text{NaOH}.

(b)(vi)

Use your answer to (v) to calculate the mass of (NH4)2SO4(\text{NH}_4)_2\text{SO}_4 that reacted with NaOH\text{NaOH}.

(b)(vii)

Hence, calculate the percentage purity of the ammonium sulfate fertiliser.

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Q22012 May/Jun·P236 partsEasy
(a)(i)

Write a balanced equation for the reaction between Na₂CO₃ and HCl.

(a)(ii)

Calculate the amount, in moles, of HCl in the 35.8 cm³ of solution used in the titration.

(a)(iii)

Use your answers to (i) and (ii) to calculate the amount, in moles, of Na₂CO₃ in the 25.0 cm³ of solution used in the titration.

(a)(iv)

Use your answer to (iii) to calculate the amount, in moles, of Na₂CO₃ in the 250 cm³ of solution in the standard volumetric flask.

(a)(v)

Hence calculate the mass of Na₂CO₃ present in 5.13 g of washing soda crystals.

(b)

Use your calculations in (a) to determine the value of x in Na₂CO₃.xH₂O.

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Q5(c)2012 May/Jun·P234MMedium
(c)

Compound F will react with sodium.

Calculate the volume of H₂, measured at room temperature and pressure, which will be produced when 0.600 g of F is reacted with an excess of Na.

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Q12012 Oct/Nov·P217 partsEasy
(a)

One salt which is used as a dietary supplement is a hydrated zinc sulfate, ZnSO4xH2O\text{ZnSO}_4\cdot x\text{H}_2\text{O}, which is a colourless crystalline solid.

Crystals of zinc sulfate may be prepared in a school or college laboratory by reacting dilute sulfuric acid with a suitable compound of zinc.

Give the formulae of two simple compounds of zinc that could each react with dilute sulfuric acid to produce zinc sulfate.

(b)(i)

Why was the boiling tube heated, cooled and reweighed four times?

(b)(ii)

Calculate the amount, in moles, of the anhydrous salt produced.

(b)(iii)

Calculate the amount, in moles, of water driven off by heating.

(b)(iv)

Use your results to (ii) and (iii) to calculate the value of xx in ZnSO4xH2O\text{ZnSO}_4\cdot x\text{H}_2\text{O}.

(c)(i)

What mass of pure crystalline zinc ethanoate (Mr=219.4M_r = 219.4) will need to be taken to obtain a dose of 15 mg15\text{ mg} of zinc?

(c)(ii)

If this dose is taken in solution as 5 cm35\text{ cm}^3 of aqueous zinc ethanoate, what would be the concentration of the solution used?

Give your answer in mol dm3\text{mol dm}^{-3}.

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Q12012 Oct/Nov·P227 partsEasy
(a)

One salt which is used as a dietary supplement is a hydrated zinc sulfate, ZnSO4xH2O\text{ZnSO}_4 \cdot x\text{H}_2\text{O}, which is a colourless crystalline solid.

Crystals of zinc sulfate may be prepared in a school or college laboratory by reacting dilute sulfuric acid with a suitable compound of zinc.

Give the formulae of two simple compounds of zinc that could each react with dilute sulfuric acid to produce zinc sulfate.

(b)(i)

Why was the boiling tube heated, cooled and reweighed four times?

(b)(ii)

Calculate the amount, in moles, of the anhydrous salt produced.

(b)(iii)

Calculate the amount, in moles, of water driven off by heating.

(b)(iv)

Use your results to (ii) and (iii) to calculate the value of xx in ZnSO4xH2O\text{ZnSO}_4 \cdot x\text{H}_2\text{O}.

(c)(i)

What mass of pure crystalline zinc ethanoate (Mr=219.4M_r = 219.4) will need to be taken to obtain a dose of 15 mg15\text{ mg} of zinc?

(c)(ii)

If this dose is taken in solution as 5 cm35\text{ cm}^3 of aqueous zinc ethanoate, what would be the concentration of the solution used?

Give your answer in mol dm3\text{mol dm}^{-3}.

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Q52011 May/Jun·P212 partsEasy
(a)

When calcium carbide is reacted with water, ethyne and calcium hydroxide are formed.

Construct a balanced equation for this reaction.

(d)(i)

Write balanced equations, with state symbols, that represent

the standard enthalpy change of combustion, ΔHc\Delta H_c^\ominus, of C₂H₂, and

..................................................................................................................

the standard enthalpy change of formation, ΔHf\Delta H_f^\ominus, of C₂H₂.

..................................................................................................................

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